Abstract:
Fundamental absorption edge spectra and reflectivity spectra of TlaAsS3, T13AsSe3 and TlaSbS 3 crystals have been investigated in the range 1-6 eV at 300 and 77 K. Polarization dependences of three excitonic series ground states have been found in
TlaAsS 3 and TI3SbS3 crystals. The energetic band structure of these crystals has been built on the basis of experimental reflectivity spectra and theoretical band calculations for crystals of C53v group.