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Band structure and optical constants of SnS2 single crystals

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dc.contributor.author RUSU, E. V.
dc.contributor.author SYRBU, N. N.
dc.contributor.author TIRON, A. V.
dc.contributor.author ZALAMAI, V. V.
dc.date.accessioned 2020-12-22T14:39:43Z
dc.date.available 2020-12-22T14:39:43Z
dc.date.issued 2019
dc.identifier.citation RUSU, E. V., SYRBU, N. N., TIRON, A. V. et al. Band structure and optical constants of SnS2 single crystals. In: Materials Research Express, 2019, V. 6, Nr. 4, pp. 046203. ISSN 1573-9228. en_US
dc.identifier.uri https://doi.org/10.1088/2053-1591/aafb25
dc.identifier.uri http://repository.utm.md/handle/5014/12255
dc.description Access full text - https://doi.org/10.1088/2053-1591/aafb25 en_US
dc.description.abstract Absorption (K), reflection (R) and wavelength modulated transmission (ΔT/Δλ) spectra in SnS2 crystals of hexagonal phase (space group P63/mmc) were investigated in temperature interval from 300 to 10 K. It was established that indirect band gap (Egind - 2.403 eV) is due to unpolarized indirect transitions between Γ and M points of Brillouin zone. A minimal direct band gap (Egdir - 2.623 eV) in E∣∣b polarization is formed by direct allowed transitions and in E⊥b polarization (2.698 eV) by forbidden transitions in Γ point of Brillouin zone. A magnitude of refractive index (n) changes from 3 to 4 and has a maximum at 2.6 eV. Optical functions (n, k, ε1 and ε2) in energy region E > Eg (3–6.5 eV) were calculated from measured reflection spectra by Kramers-Kronig analysis. Features observed in reflection and optical function spectra were assigned to electron transitions. This electron transitions were localized in framework of theoretically calculated band struct. en_US
dc.language.iso en en_US
dc.publisher IOP Publishing en_US
dc.rights Attribution-NonCommercial-NoDerivs 3.0 United States *
dc.rights.uri http://creativecommons.org/licenses/by-nc-nd/3.0/us/ *
dc.subject spectra en_US
dc.subject crystals en_US
dc.subject electron transitions en_US
dc.title Band structure and optical constants of SnS2 single crystals en_US
dc.type Article en_US


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