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IR absorption by free carriers in nanostructured organic crystals of tetrathiotetracene-iodide

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dc.contributor.author CASIAN, Anatolie
dc.date.accessioned 2022-05-13T10:50:18Z
dc.date.available 2022-05-13T10:50:18Z
dc.date.issued 2015
dc.identifier.citation CASIAN, Anatolie. IR absorption by free carriers in nanostructured organic crystals of tetrathiotetracene-iodide. In: Science and Society- the Use of Light: Workshop în cadrul conf. ICNBME - International Conference on Nanotechnologies and Biomedical Engineering, 24-25 Sept, 2015, Chişinău, Republic of Moldova: Abstracts, 2015, p. 15. en_US
dc.identifier.uri http://repository.utm.md/handle/5014/20280
dc.description Only Abstract
dc.description.abstract The coefficient of long wave infra red (IR) absorption α is calculated for nanostructured organic crystals of tetrathiotetracene-iodide, TTT2I3, at room temperature as a function of radiation frequency v in the interval from 1012 Hz to 1013 Hz. In this interval the lattice absorption is still weak. Two the most important interaction mechanisms of carriers with longitudinal acoustic phonons are considered. One is of deformation potential type, and the second is similar to that of polaron. The carriers scattering on impurities is described by the dimensionless parameter D which is proportional to impurity concentration. Calculations are made for crystals with different values of D and different values of the dimensionless parameter γ which is the ratio of amplitudes of both electron-phonon interactions. In not very pure crystals, α slowly decreases almost linearly with the increase of v. In more perfect crystals the dependences of α on v become more complicated. Due to the increase of phase delay of carrier distribution function with respect to the phase of electrical field, when v increases, the absorption decreases. The decrease is more pronounced in purer crystal, where relaxation time is higher. Only in the purest crystal (with D = 0.01 and γ = 1.5) at v > 5· 1012 Hz the frequency dependence becomes very close to v -2 (Drude law), due to the increase of contribution of carriers with energies near the maximum of the relaxation time. en_US
dc.language.iso en en_US
dc.publisher Technical University of Moldova en_US
dc.rights Attribution-NonCommercial-NoDerivs 3.0 United States *
dc.rights.uri http://creativecommons.org/licenses/by-nc-nd/3.0/us/ *
dc.subject infra red absorption en_US
dc.subject organic crystals en_US
dc.subject crystals en_US
dc.subject tetrathiotetracene-iodide crystals en_US
dc.title IR absorption by free carriers in nanostructured organic crystals of tetrathiotetracene-iodide en_US
dc.type Article en_US


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